Catalysis of Organic Reactions

By: Robert L. Augustine (Editor)

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Hardcover | 12 July 1985 | Edition Number 1

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Hardcover
420 Pages

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23.4 x 15.6 x 2.39

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Uniting the work of over 20 leading international authorities, this outstanding source provides a complete updating of important developments in the study of catalysis as it applies to organic synthesis -- with applications in major industrial processes. In self-contained chapters that include an abstract, introduction, discussion, conclusion, and detailed references, this book covers a broad variety of catalytic processes -- both homogeneous and heterogeneous. Comprehensive and definitive, this work contains practical information on asymmetric catalytic hydrogenation ... organoactinide complexes on aumina ... amphora catalysts ... phenol hydrogenation process ... and much more. Packed with useful illustrations, schemes, tables, and equations, Catalysis of Organic Reactions will benefit the work of chemical engineers; organic chemists; industrial researchers in chemical process technologies; academic researchers in the catalytic sciences; organometallic and coordination chemists; and students in chemical engineering, organic chemistry, and inorganic chemistry. Book jacket.

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Preface	p. iii
Contributors	p. xi
Homogeneous Catalysis
Mechanism and Stereochemistry of Asymmetric Catalytic Hydrogenation	p. 3
Asymmetric Hydroformylation Via Polymer-Supported Chiral Catalysts	p. 23
Selective CH and CC Bond Activation in Alkanes by Transition Metal Complexes	p. 37
Catalytic Methods for the Synthesis of Cyclopropanes	p. 47
The Interactions of Quinoline and Tetrahydroquinoline with Catalysts. Modeling Heterogeneous Catalysts with Homogeneous Catalysts. 4.1	p. 73
H[subscript 2]-Co Reactions
Methanol Synthesis over Supported Palladium Catalysts	p. 95
Supported Metal Cluster Catalysts for Synthesis Gas Conversion	p. 115
CO Hydrogenation on Alkali-Promoted Nickel Catalysts	p. 135
1,4-Butanediol Via Rhodium Carbonyl-Catalyzed Hydroformylation of Allyl Alcohol and Allyl t-Butyl Ether	p. 151
Heterogeneous Catalysis
Single Crystals as Model Catalysts	p. 171
Asymmetric Sites on Heterogeneous Catalysts	p. 189
Organoactinide Complexes on Alumina	p. 207
Solvated Metal Atom Dispersed (SMAD) Catalysts Highly Active Bimetallic Systems	p. 225
Amphora Catalysts	p. 251
Catalytic Oxidation
Industrial Uses of Catalytic Oxidation and the Direct Oxidation of Olefins to Glycols	p. 269
Mechanistic Studies of the Selective Oxygen Oxidation of Sulfides to Sulfoxides Catalyzed by Dihalo Ruthenium(II) Complexes	p. 281
Asymmetric Epoxidation	p. 295
C-C Double Bond Cleavage by Molecular Oxygen	p. 309
Oxidation of Hydrocarbons by Methane-Utilizing Bacteria	p. 327
Selected Topics
Phenol Hydrogenation Process	p. 355
Preparation of Nitriles by Catalyzed Dehydration of Carboxamides and Aldoximes	p. 373
Aminomethylation of Diene Polymers: Novel Route to Polyamines	p. 381
Index	p. 391
Table of Contents provided by Ingram. All Rights Reserved.

Catalysis of Organic Reactions

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Hardcover

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