Electrical Fluctuations in Polyelectrolytes

Chapter 1. The Electrical Capacitance, the Link to the Electrical Fluctuations 1.1 Electrical fluctuations 1.2 The Fluctuation-Dissipation Theorem 1.2.1 Electrical circuit 1.3 The electrical capacitance 1.3.1 Capacitance definition Chapter 2. Electrical Fluctuations in Colloid and Ionic Solutions 2.1 Electrical fluctuations in solutions 2.2 Calculation of the electrical mean squares fluctuations 2.3 Calculation of the spectral density fluctuations 2.4 Calculation of the mean squares temporal averages Chapter 3. Electrical Fluctuations Around a Charged Colloidal Cylinder in an Electrolyte 3.1 Electrical fluctuations perpendicular to the polyelectrolyte axis Chapter 4. Dielectric Relaxation Around a Charged Colloidal Cylinder in an Electrolyte 4.1 Method 4.2 Polarizability of the Debye-Huckel Atmosphere Chapter 5. The Polarizability of Rodlike Polyelectrolytes: An Electric Circuit View 5.1 Longitudinal electrical fluctuations and the polarizability of rodlike polyelectrolytes 5.2 The longitudinal polarizability Chapter 6. pH Fluctuations in Unilamellar Vesicles 6.1 pH sensitivity of the fluorescence response 6.2 General Model 6.3 Electrical properties of the system 6.3.1 Ionizable groups 6.3.2 Electrical and polarization shift in the fluorescence spectrum 6.3.3 Buffer capacity 6.4 pH Fluctuations Chapter 7. Electrical Fluctuations on the Surfaces of Proteins from Hydrodynamic Data 7.1 Electrical fluctuations on the surface of proteins from hydrodynamic data 7.2 The Fluctuation-Dissipation Theorem 7.3 Relation between capacitance and electrical fluctuations 7.4 Relation between friction coefficient and capacitance 7.5 Relation between polarizability and intrinsic viscosity 7.6 Relations of the polarizability to electric field and dipole moment fluctuations