List of Contributors.
Foreword.
1. Applications of Crystal Engineering Strategies in
Solvent-free Reactions: Toward a Supramolecular Green
Chemistry.
1 Introduction.
1 Mechanochemical preparation of Hydrogen-Bonded Adducts.
1 Mechanically induced formation of covalent bonds.
1 The solvent-free chemistry of the zwitterion.
1 Concluding remarks.
1 Acknowledgements.
References.
2. Crystal Engineering of Pharmaceutical Co-crystals.
1 Introduction.
2 What is the origin of polymorphism and is it prevalent in
co-crystals?.
3 What is the pharmaceutical co-crystal?.
4 Conclusions.
5 Acknowledgements.
References.
3. Template-controlled Solid-state Synthesis: Toward a
General Form of Covalent Capture in Molecular Solids.
1 Introduction.
2 Controlling reactivity using linear templates.
3 Template-controlled solid-state reactivity.
4 Target-oriented organic synthesis in the organic state.
5 Other linear templates.
6 Summary and outlook.
References.
4. Interplay of Non-covalent Bonds: Effect of Crystal
Structure on Molecular Structure.
1 Introduction.
2 Second-sphere coordination.
3 Soft coordination environments.
4 Speciation.
5 Molecular conformation.
6 Conclusions.
References.
5. Crystal Engineering of Halogenated Heteroaromatic
Clathrate Systems.
1 Introduction.
2 Aromatic edge-edge C-H...N dimers.
3 Heteroatom-1,3-peri interactions.
4 Molecular pen structures.
5 Halogenated edge-edge interactions.
6 Pi-halogen dimer (PHD) interactions.
7 Molecular bricks, spheres and grids.
8 Conclusions.
9 Acknowledgements.
References.
6. Steric Control over Supramolecular Aggregation: A Design
Element in Crystal Engineering?
1 Introduction.
2 Diorganotin carboxylates.
3 Triorganotin carboxylates.
4 Binary zinc xanthates.
5 Bipyridine adducts of zinc dithiophosphates.
6 Binary mercury dithiocarbamates.
7 Binary bismuth xanthates.
8 Conclusions and Outlook.
9 Acknowledgements.
References.
7. Incorporating Molecular Hosts into Network
Structures.
1 Introduction.
2 Hydrogen-bonded structures with CTV.
3 Coordination polymers.
4 Extended-arm CTV derivatives and their coordination
polymers.
5 Conclusions.
6 Acknowledgements.
References.
8. Interpenetrating Networks.
1 Introduction.
2 Notation.
3 1-D nets.
4 2-D nets.
5 3-D nets.
6 Unusual interpenetration.
7 Consequences of interpenetration.
8 Self-penetration.
9 Entangled but not interpenetrating.
10 Conclusions.
References.
9. Architecture and Functional Engineering Based on
Paddlewheel Dinuclear Tetracarboxylate Building Blocks.
1 Introduction.
2 Synthetic strategy.
3 Architecture engineering based on preorganized building
blocks.
4 Conductive and magnetic properties based on preorganized
building blocks.
5 Porous properties based on preorganized and in situ building
blocks.
6 Conclusion and outlook.
References.
10. Supramolecular Interactions in Directing and Sustaining
Coordination Molecular Architectures.
1 Introduction.
2 Molecular architectures assembled by hydrogen-bonding
interactions.
3 Molecular architectures assembled VIA ... Interactions.
4 Metallophilic interactions.
5 Concluding remarks and outlooks.
6 Acknowledgements.
References.
11. The Structure-directing Influence of Hydrogen Bonding in
Coordination Polymers.
1 Introduction.
2 A novel cadmium cyanide network.
3 Dihydroxybenzoquinone and Chloranilic acid derivatives of
Lanthanides.
4 A stable zinc saccharate network.
5 Anionic metal-carbonate networks.
6 Conclusions.
References.
12. Hydrogen-bonded Coordination Polymeric
Structures.
1 Introduction.
2 Solid-state supramolecular transformation of hydrogen-bonded
3-D network to 3-D coordination polymetric network structures by
thermal dehydration.
3 Interconvertible solid-state supramolecular
transformation.
4 Solid-state transformation of a helical coordination
polymetric structure to a 3-D coordination network structure by
thermal dehydration.
5 Influence of chiral centers on the helicity of the
coordination polymers.
6 Consequences of C=O... interactions.
7 Supramolecular isomerism.
8 Starlike channels and hexagonal diamondoid topology.
9 Hydrogen-bonded helical water molecules inside a staircase 1-D
coordination polymer.
10 Hydrogen-bonded polyrotaxane-like structure containing cyclic
(H2O)4 in [Zn(OAc)2(m-bpe)].2H2O.
11 Summary.
12 Acknowledgements.
References.
Index.
