Homo- and Heterobimetallic Complexes in Catalysis

Cooperative Catalysis

By: Philippe Kalck (Editor)

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Hardcover | 23 June 2016

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Hardcover
292 Pages

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23.39 x 15.6 x 1.75

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Bimetallic templates to perform catalysis: the case of ethylene polymerization and hydroamination.- Functionalization of alkynes mediated by bimetallic catalysts. Nucleophilic additions, cross-coupling reactions, addition reactions, pericyclic reactions.- Dinuclear rhodium complexes in the hydroformylation reaction of alkenes.- Early-Late bimetallic complexes in functionalization reactions. Cyclopropanation of styrene (Ta-Ru), Kumada coupling of unactivated alkyl chlorides with alkyl Grignard reagents (Zr-Co), Hydrosilylation of ketones (Zr-Co, Ti-Rh, Nb-Rh).- Transmission of the electronic information through the metal-metal bond in dinuclear templates. CH activation (RuI), epoxidation of alkenes (RhII).- Hydrogenation reactions catalyzed by di-rhodium and di-iridium complexes. Alkynes, alkenes, imines.- Biomimetic complexes for the production of dihydrogen, reduction of CO2.- Synergism introduced by a second metal in catalysis. Reactivation of the catalyst; Catalytic binuclear elimination reaction. Hydroformylation, carbonylation of methanol.

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