Preface | p. iii |
Contributors to Volume 17 | p. vii |
Contents of Other Volumes | p. xiii |
Applications of Supercritical Fluid Solvents in the Pharmaceutical Industry | p. 1 |
Scope | p. 1 |
Supercritical Fluid Solvent Properties | p. 2 |
Applications of SCF as Extraction/Fractionation Solvents | p. 7 |
Applications of SCF as Chromatography Eluents | p. 12 |
Applications of SCF as Reaction Media | p. 13 |
Pollution Abatement | p. 14 |
Applications of SCF for Particle Design and Drug Formulation | p. 15 |
Biological Applications | p. 26 |
Future Trends | p. 27 |
References | p. 28 |
Reactive Solvent Extraction | p. 37 |
Introduction | p. 37 |
Reactive Solvent Extraction Equilibria | p. 48 |
Reactive Mass Transfer | p. 58 |
Solvent Extraction Equipment | p. 68 |
Concluding Remarks | p. 76 |
References | p. 77 |
Symmetrical P,P'-Disubstituted Esters of Alkylenediphosphonic Acids as Reagents for Metal Solvent Extraction | p. 85 |
Introduction | p. 85 |
Synthesis | p. 87 |
Spectroscopic Studies | p. 94 |
Aggregation Studies | p. 103 |
Solvent Extraction of Metal Ions at Low Loading | p. 110 |
Solvent Extraction of Metal Ions at High Loading | p. 120 |
Enthalpy and Entropy Changes in Metal Solvent Extraction | p. 126 |
Intra-Lanthanide Ion Separations | p. 132 |
Synergistic Extraction of Metal Ions | p. 138 |
Extraction Chromatographic Applications | p. 145 |
Reagents for Use in Supercritical Fluid Extraction | p. 149 |
Conclusions | p. 155 |
Nomenclature | p. 157 |
References | p. 158 |
Sulfoxide Extractants and Synergists | p. 165 |
Introduction | p. 165 |
Extraction from Nitrate Media | p. 169 |
Extraction from Chloride Media | p. 195 |
Extraction from Other Media | p. 209 |
Selectivity of the Extraction | p. 213 |
Interfering Phenomena | p. 217 |
Synergism | p. 221 |
Nomenclature | p. 233 |
Physical Properties of Sulfoxides | p. 234 |
References | p. 236 |
Extraction with Metal Bis(dicarbollide) Anions: Metal Bis(dicarbollide) Extractants and Their Applications in Separation Chemistry | p. 243 |
Introduction | p. 243 |
Synthesis and Properties of Metal Bis(dicarbollide)s and Other Cluster Boron Compounds Aimed for Extraction Purposes | p. 247 |
Extraction with Basic and Halogenated Cobalt Bis(dicarbollide)s | p. 282 |
Extraction with Cobalt Bis(dicarbollide)s and Synergists | p. 283 |
Extraction with Functionalized Metal Bis(dicarbollide)s and Other Boron Extractants | p. 299 |
Chloro-Protected Bis(dicarbollide) Technologies for Extraction of Fission Products and Actinide Cations from Radioactive Wastes | p. 306 |
Analytical and Other Applications of Extraction Systems with Metal Bis(dicarbollide)s | p. 312 |
Conclusions | p. 322 |
Supplementary Material | p. 322 |
Symbols | p. 323 |
References | p. 324 |
Principles of Extraction of Electrolytes | p. 335 |
Introduction | p. 335 |
Aims and Scope of the Review | p. 338 |
Description of the Systems | p. 338 |
Characteristic Examples of Equilibria in Extraction of Electrolytes | p. 343 |
Gibbs Energies of Transfer and Some Semiempirical Models | p. 357 |
Conclusions | p. 378 |
Symbols | p. 378 |
References | p. 381 |
Index | p. 387 |
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