Reinforcement Materials | p. 1 |
Reinforcement Materials - Rigid | p. 1 |
Glass | p. 1 |
Glass Composition | p. 2 |
D-Glass | p. 2 |
E-Glass | p. 3 |
S-Glass | p. 4 |
Quartz | p. 4 |
Glass Fiber Manufacturing | p. 5 |
From Yarn to Fabric | p. 7 |
Glass Types and Construction | p. 7 |
Glass Fabric Weave | p. 9 |
Plain Weave | p. 9 |
Twill Weave | p. 9 |
Long-Shaft Satin | p. 10 |
Basket Weave | p. 10 |
Leno Weave | p. 11 |
Surfacing Mat, Paper, or Veil | p. 11 |
Glass Fiber Paper | p. 12 |
Quartz | p. 12 |
Properties of Glass Fabrics | p. 13 |
Moisture and Chemical Resistance | p. 13 |
Electrical Properties | p. 13 |
Heat and Fire Resistance | p. 14 |
Thermal Conductivity | p. 14 |
Aramids | p. 14 |
Nonwoven Aramid (Thermount) | p. 14 |
Constraining Dielectric Materials (Kevlar) | p. 16 |
References | p. 19 |
Resins | p. 21 |
Introduction | p. 21 |
Polyester Resin | p. 22 |
Epoxy | p. 23 |
Difunctional Epoxy | p. 24 |
Multifunctional Epoxy | p. 25 |
General-Purpose Systems Having a Tg between 135 and 145[degree]C | p. 26 |
Higher-Performance Multifunctional Epoxies with a Tg between 150 and 165[degree]C | p. 26 |
High-Temperature Multifunctional Epoxy with a Tg between 170 and 185[degree]C | p. 27 |
Tetrafunctional Epoxy | p. 27 |
Curing Agent | p. 27 |
High-Tg Epoxy | p. 30 |
Polyimide | p. 31 |
Epoxy-Blended Polyimide | p. 32 |
Cyanate Ester and Cyanate Ester Blends (BT Resin) | p. 33 |
Cyanate Ester Resins | p. 33 |
Polyphenylene Oxide (PPO) Epoxy Blends | p. 34 |
Getek Resins | p. 35 |
Polytetrafluoroethylene Resin (PTFE) | p. 35 |
References | p. 37 |
Flexible Films | p. 39 |
Introduction | p. 39 |
Types of Flexible Materials | p. 40 |
Polyethylene Terephthalate ([PET] Polyester) | p. 40 |
Polyester/Epoxy | p. 42 |
Polyethylene Naphthalate (PEN) | p. 42 |
Fluorocarbons (FEP) | p. 42 |
Polyimide | p. 44 |
Tear Resistance | p. 45 |
Dimensional Stability | p. 45 |
Aramid | p. 46 |
Adhesives | p. 48 |
Types and Use of Adhesive | p. 49 |
Coating Process (Adhesive) | p. 50 |
Major Adhesive Types | p. 50 |
Adhesiveless Systems | p. 52 |
Cast to Foil | p. 53 |
Vapor Deposition on Film | p. 53 |
Direct Vapor/Sputter Metallization onto Polyimide Film | p. 53 |
Plated on Film | p. 54 |
Adhesiveless Properties | p. 54 |
Electrical Advantage | p. 54 |
Mechanical Advantage | p. 55 |
Thermal Advantage | p. 55 |
Cover Coat/Cover Layer | p. 55 |
Bond Plies | p. 57 |
Conductive Materials | p. 57 |
Electrodeposited Copper | p. 58 |
Rolled Annealed Copper (RA) | p. 59 |
Copper-Clad Laminates | p. 59 |
References | p. 63 |
Copper Foils | p. 65 |
Introduction | p. 65 |
Electrodeposited Copper Foil (also called ED foil) | p. 65 |
Rolled Copper Foils (also called RA foil) | p. 67 |
Fabricating Rolled Copper Foils | p. 67 |
Foil Treatment | p. 69 |
Heat Treatment | p. 69 |
Foil Processing | p. 69 |
Grades | p. 71 |
Electrodeposited | p. 71 |
Grade-1 or Standard Electrodeposited (STD-Type E) | p. 71 |
Grade-2 or High-Ductility Electrodeposited Foils (HDE-Type E) | p. 71 |
Grade-3 or High-Temperature Elongation Foil (HTE-Type E) | p. 72 |
Grade-4 Annealed Electrodeposited or "Super High Duct" (ANN-Type E) | p. 73 |
Rolled Copper Foil | p. 73 |
Grade-5 "As Rolled" Wrought Copper (AR-Type W) | p. 73 |
Grade-6 or Light Cold Rolled Wrought (LCR-Type W Special Temper) | p. 73 |
Grade-7 or Rolled Annealed Wrought (ANN-Type W) | p. 74 |
Grade-8 or "As Rolled" Wrought Low- Temperature Annealable (Type LTA) | p. 75 |
Properties | p. 75 |
Application | p. 75 |
Nickel Foil | p. 75 |
References | p. 76 |
Laminates, Rigid | p. 77 |
Introduction | p. 77 |
NEMA Grades | p. 77 |
Paper-Based Laminates | p. 77 |
Types of Laminates | p. 78 |
XPC | p. 78 |
XXXPC | p. 79 |
FR-1 | p. 79 |
FR-2 | p. 79 |
FR-3 | p. 80 |
Properties, Construction, and Specifications (Paper-Based Laminates) | p. 80 |
Processing Paper-Grade Laminates | p. 80 |
Composite Laminates | p. 80 |
Reinforcing Mats | p. 82 |
Surfacing Mats, Paper, or Veil | p. 86 |
Glass Fiber "Paper" | p. 86 |
Polyester Glass Mat | p. 86 |
Types of Composite Laminate | p. 87 |
CEM-1 | p. 87 |
CEM-3 | p. 87 |
CRM-5 | p. 87 |
FR-6 | p. 88 |
Properties, Construction, and Specifications (Composite Laminates) | p. 88 |
Storage | p. 88 |
Material Recommendation | p. 92 |
Rigid Laminates (Glass-Reinforced) | p. 92 |
Electrical Characteristics | p. 94 |
Laminate Thickness | p. 94 |
Laminates, Rigid Glass Reinforcement | p. 95 |
Epoxy Laminate (FR-4) | p. 95 |
Difunctional Epoxies | p. 96 |
Cyanate Ester | p. 98 |
Polyimide Laminates | p. 100 |
Polyimide/Glass | p. 100 |
Polyimide Glass and Copper-Invar-Copper | p. 101 |
Polyimide Quartz | p. 101 |
Polyphenylene Oxide (PPO) | p. 102 |
Aramid Laminates | p. 102 |
Epoxy Thermount | p. 102 |
Multifunctional Epoxy/Nonwoven Aramid Reinforcement | p. 104 |
Epoxy on Woven Kevlar | p. 104 |
Prepreg | p. 106 |
Manufacturing Prepreg | p. 106 |
Additive Laminates | p. 107 |
Additive Circuitry | p. 107 |
Semiadditive Laminates | p. 107 |
Ultrathin Copper Foil Clad | p. 108 |
Unclad | p. 108 |
Unclad or Adhesive-Coated | p. 109 |
Catalytic or Seeded | p. 109 |
References | p. 110 |
High-Speed/High-Frequency Laminates | p. 113 |
Introduction | p. 113 |
High-Speed/High-Frequency Laminates | p. 113 |
RF Analog Circuit Characteristics | p. 114 |
Digital Circuit Characteristics | p. 114 |
Two Major Classes of Reinforcements | p. 114 |
Goal of Each Application Area | p. 115 |
Thin Laminates | p. 116 |
Resins | p. 116 |
Polytetrafluoroethylene Laminates | p. 116 |
Ceramic-Filled Polytetrafluoroethylene | p. 120 |
New Fluoropolymer Composite Materials | p. 120 |
Epoxy Resin | p. 122 |
High-Frequency Laminate Designations | p. 122 |
GRN Type Laminates with Glass Microfibers | p. 122 |
GRN Type Laminates with Nonwoven Fiberglass | p. 123 |
GTN Type Laminates with E-Glass | p. 124 |
Type GXN Laminates with E-Glass | p. 124 |
GYN Type Laminates with E-Glass | p. 125 |
High-Dk (6.0 to 10.5) Laminates with E-Glass | p. 126 |
Temperature-Stable Dielectric Constant and Low-CTE Laminates with E-Glass | p. 127 |
Commercial-Grade Laminates | p. 128 |
Laminate Construction | p. 129 |
Cross-Plied and Non-Cross-Plied Construction (meet type GT) | p. 129 |
Bonding | p. 130 |
Dimensional Stability | p. 130 |
Drilling | p. 131 |
References | p. 131 |
Metal Core and Constraining Core Materials | p. 133 |
Introduction | p. 133 |
Copper-Invar-Copper (CIC) | p. 134 |
Copper-Molybdenum-Copper (CMC) | p. 135 |
Silicon Carbide-Reinforced Aluminum (SiC/Al) | p. 138 |
Coefficient of Thermal Expansion Trade-Offs (CTE) | p. 140 |
References | p. 141 |
Abbreviations, Definitions, and Terms | p. 143 |
Index | p. 153 |
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