Nanoscale Materials | p. 1 |
Chemically Functionalized Metal Nanoparticles: Synthesis, Properties and Applications | p. 5 |
Introduction | p. 5 |
Synthesis and Properties of Monolayer Capped Metal Nanoparticles | p. 6 |
Synthesis and Properties of Polymer-Capped Metal Nanoparticles | p. 16 |
Controlling the Size and Composition of the Metallic Cores of Nanoparticles | p. 19 |
Catalytic, Electrochemical and Photochemical Properties of Functionalized Metal Nanoparticles | p. 22 |
Functionalized Metal Nanoparticle Arrays on Surfaces | p. 37 |
Conclusions and Perspectives | p. 63 |
Acknowledgment | p. 64 |
References | p. 64 |
Metal Nanoparticles for Catalysis | p. 79 |
Introduction | p. 79 |
Metals as Catalysts | p. 80 |
Preparation of Metal Nanoparticles | p. 81 |
Characterization of Metal Nanoparticle Catalysts | p. 85 |
Effect of Structures on Catalysis of Metal Nanoparticles | p. 86 |
Effect of Polymer Field on Catalysis of Metal Nanoparticles | p. 92 |
Concluding Remarks and Future Aspects | p. 94 |
References | p. 94 |
Ultrafast Dynamics of Metal Nanospheres and Nanorods | p. 97 |
Introduction | p. 97 |
Experimental Techniques | p. 100 |
Results and Discussion | p. 101 |
Summary and Conclusions | p. 114 |
Acknowledgements | p. 115 |
References | p. 115 |
Radiation Effects in Nanoparticle Suspensions | p. 119 |
Introduction | p. 119 |
Energy Deposition in Particle Suspensions | p. 121 |
Experimental Procedures | p. 123 |
Escape of Electrons Into the Aqueous Phase | p. 124 |
Escape of Holes Into the Aqueous Phase | p. 125 |
Interfacial Capture | p. 126 |
Hydrogen Yields | p. 127 |
Radiolysis as a Synthetic Tool | p. 130 |
Conclusions | p. 131 |
Acknowledgement | p. 132 |
References | p. 132 |
Synthesis of Nanoparticles in Microemulsions | p. 135 |
Introduction | p. 135 |
Mechanism of Formation of Particles in Microemulsions | p. 136 |
Monte Carlo Simulation | p. 144 |
Examples | p. 152 |
Conclusions and Future Perspectives | p. 153 |
Acknowledgements | p. 153 |
References | p. 153 |
Chemical Aspects of Semiconductor Nanocrystals | p. 157 |
Introduction | p. 157 |
Structural, Electronic and Optical Properties | p. 158 |
Chemical Synthesis of Semiconductor Nanocrystals | p. 162 |
Surface Chemistry and Assembly Methods | p. 169 |
Conclusions and Outlook | p. 175 |
References | p. 176 |
Spectroelectrochemistry of Semiconductor Colloid Quantum Dots | p. 181 |
Introduction | p. 181 |
Charging and Semicondutor Quantum Dots | p. 182 |
Spectroelectrochemistry of Colloid Quantum Dots | p. 183 |
Conclusions | p. 187 |
Acknowledgements | p. 187 |
References | p. 188 |
Nanoparticles with Polymeric Surfaces--Fillers and Models for Ultrasoft Colloids | p. 191 |
Introduction | p. 191 |
Synthesis of Model Particles | p. 192 |
Compatibility of Colloidal Particles and Linear Chains | p. 194 |
Ultrasoft Colloids in Coloid-Polymer-Blends | p. 198 |
Concluding Remarks | p. 206 |
Acknowledgments | p. 206 |
References | p. 206 |
Properties of Nipam-based Intelligent Microgel Particles: Investigated Using Scattering Methods | p. 209 |
Introduction | p. 209 |
Microgel Preparation | p. 210 |
Scattering Methods | p. 211 |
Summary and Outlook | p. 222 |
Acknowledgments | p. 223 |
References | p. 223 |
Design of Nanoscale Materials Using Silica-coated Metal Nanocolloids | p. 227 |
Introduction | p. 227 |
Modelling of Optical Properties | p. 229 |
Thin Films Through Layer-by-layer Assembly | p. 232 |
Nanoparticle Assembly on Colloid Spheres | p. 234 |
Doped Glass from Coated Nanoparticles | p. 236 |
Ordered Three-dimensional Assemblies | p. 238 |
Conclusions and Outlook | p. 244 |
Acknowledgments | p. 244 |
References | p. 244 |
Fabrication of Inorganicnanocomposites Using Self-assembly and Sol-gel Processing | p. 247 |
Introduction | p. 247 |
Gold-polypyrrole Core-shell Nanocomposites Through Self-assembly of Block-copolymers | p. 251 |
Nonlinear Optical Properties of Au/SiO[subscript 2] Composites | p. 253 |
Luminescence of Eu[superscript +3]-doped Silica Composites | p. 255 |
Photophysics of Quantum Dots | p. 258 |
Highly Luminescent Qd-glasses | p. 259 |
Silica-coated Quantum Dots | p. 262 |
Summary and Outlook | p. 266 |
Acknowledgements | p. 266 |
References | p. 267 |
Organization of Layer-by-layer Assembled Nanocomposites: Functional Effects in Photonics and Biomaterials | p. 273 |
Introduction | p. 273 |
Layer-by-layer Assembly | p. 273 |
Ordering of the Lbl Assembled Nanomaterials | p. 275 |
Lateral Ordering in Lbl Films | p. 284 |
Conclusions | p. 296 |
References | p. 297 |
New Applications and Properties of Langmuir-blodgett Films | p. 303 |
Introduction | p. 303 |
Liquid Crystals | p. 306 |
Luminescence Properties: Organic Light-emitting Diodes | p. 312 |
Magnetic Properties | p. 320 |
Nonlinear Optical Properties | p. 326 |
References | p. 330 |
Assemblies of Magnetic Particles | p. 335 |
Introduction | p. 335 |
Theory | p. 337 |
Wet Chemical Synthesis of Magnetic Nanoparticles | p. 347 |
Assembling Magnetic Particles | p. 352 |
Conclusions | p. 365 |
Acknowledgment | p. 365 |
References | p. 366 |
Magnetic Nanostructures from Clusters | p. 371 |
Introduction | p. 371 |
Magnetic Nanostructure Preparation by Lecbd | p. 373 |
Structures and Morphologies of Cluster-assembled Films | p. 375 |
Magnetic Properties of Individual Clusters and Cluster-assembled Films | p. 382 |
Functionalized Magnetic Nanostructures from Mixed Clusters | p. 390 |
Conclusions | p. 392 |
References | p. 392 |
Magnetic Thin Films | p. 395 |
Introduction | p. 395 |
Film Growth | p. 396 |
Magnetic Moment (T = 0K) | p. 398 |
Magnetic Anisotropy Energy Density (T = 0K) | p. 405 |
Temperature Dependent Phenomena | p. 417 |
Conclusion | p. 419 |
Acknowledgement | p. 419 |
References | p. 420 |
Three-dimensional Photonic Crystals Made from Colloids | p. 423 |
Introduction | p. 423 |
Optical Properties of Photonic Crystals | p. 425 |
Fabrication of Photonic Crystals | p. 433 |
Engineering of Colloidal Particles: Core-shell, Metallo-dielectric, and anisotropic colloids | p. 443 |
Conclusions | p. 446 |
Acknowledgements | p. 446 |
References | p. 447 |
Fundamentals and Technological Aspects of Carbon Nanotubes | p. 455 |
Introduction | p. 455 |
Synthesis of Carbon Nanotubes | p. 456 |
Structure of Carbon Nanotubes | p. 460 |
Physical Properties and Applications of Carbon Nanotubes | p. 463 |
Applications Involving Carbon Nanotubes | p. 468 |
The Future of Carbon Nanotubes | p. 470 |
References | p. 471 |
Molecular Assembly of Fullerenes as Nanoclusters and Nanostructured Films | p. 475 |
Introduction | p. 475 |
Preparation of Fullerene Nanoclusters and Nanostructured Films | p. 476 |
Properties of Fullerene Clusters | p. 478 |
Nanostructured Fullerene Films | p. 482 |
Applications | p. 486 |
Acknowledgement | p. 491 |
References | p. 491 |
Index | p. 495 |
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