Preface | p. v |
IR spectroscopy of hydrides and its application to hydrogen bonding and proton transfer studies | p. 1 |
Introduction | p. 1 |
M-H stretching vibrations | p. 2 |
Hydrogen bonding and proton transfer | p. 11 |
Conclusions | p. 24 |
References | p. 25 |
Raman spectroscopy of graphene | p. 29 |
Introduction | p. 29 |
Graphene | p. 30 |
Raman spectroscopy | p. 34 |
Other spectroscopic techniques | p. 49 |
Conclusions | p. 52 |
Acknowledgments | p. 53 |
References | p. 53 |
Solid-state NMR: a key tool for the understanding at a molecular level of well-defined heterogeneous catalysts and surface chemistry on top of oxide materials | p. 57 |
ID NMR of spin 1/2 nuclei | p. 58 |
Chemical shift anisotropy for the molecular comprehension of the active sites (structure and dynamics) | p. 63 |
NMR of quadrupolar nuclei (spin > 1/2) | p. 65 |
Connectivity by multidimensional NMR | p. 69 |
Measuring J coupling constants and structural considerations | p. 73 |
Surface enhanced solid-state NMR spectroscopy | p. 75 |
Conclusions | p. 79 |
References | p. 79 |
Raman spectroscopy for solid oxide fuel cells | p. 84 |
Introduction and overview | p. 84 |
The solid oxide fuel cell | p. 85 |
Ex-situ characterisation studies | p. 87 |
In-situ characterisation studies | p. 108 |
Conclusion and outlook | p. 116 |
References | p. 116 |
Integrated analytical techniques for analysing individual environmental particles | p. 123 |
Introduction | p. 123 |
First era: CCSEM/EDX or EPXMA for SPA | p. 125 |
Second era: low-Z and beam sensitive particles | p. 128 |
Third era: the addition of complementary techniques | p. 130 |
Expectations and challenges for the future | p. 136 |
References | p. 138 |
Materials sciences using synchrotron infrared light sources | p. 141 |
Introduction | p. 141 |
Synchrotron infrared sources | p. 142 |
Synchrotron IR opportunities in polymer science | p. 143 |
Synchrotron IR studies in catalysis | p. 148 |
Synchrotron IR studies in extreme conditions | p. 152 |
Synchrotron IR ellipsometry | p. 155 |
Novel condensed matter compounds | p. 157 |
Some future directions | p. 159 |
Conclusions | p. 162 |
References | p. 162 |
Metal-based molecular switches generated from dithienyl ethene (DTE) | p. 166 |
Introduction | p. 166 |
Pendant Pt(II) acetylides | p. 188 |
Alternative metal acetylides (Au(I), Ru(II), CpFe) | p. 195 |
Coordinating acac-derived metal complexes | p. 200 |
Future directions | p. 204 |
References | p. 214 |
Nuclear quadrupole resonance spectroscopy | p. 216 |
Introduction | p. 216 |
Main group elements | p. 216 |
Transition metals | p. 223 |
References | p. 226 |
Simulation of spectroscopic properties of inorganic compounds | p. 229 |
Introduction | p. 229 |
Main groups | p. 232 |
Transition metals | p. 235 |
Lanthanides and actinides | p. 247 |
Summary and future directions | p. 249 |
References | p. 249 |
Combined time-resolved X-ray scattering and spectroscopy methods | p. 257 |
Introduction | p. 257 |
Synchrotron radiation | p. 258 |
X-ray scattering | p. 260 |
X-ray spectroscopy | p. 265 |
Technique combinations experimental issues | p. 270 |
Technique combinations examples | p. 275 |
Conclusions | p. 284 |
Acknowledgements | p. 284 |
References | p. 285 |
Solid state NMR of immobilized catalysts and nanocatalysts | p. 289 |
Introduction | p. 289 |
Solid state NMR spectroscopy | p. 293 |
Applications to immobilized catalysts | p. 296 |
Characterization of reaction intermediates in heterogeneous catalysis by solid state NMR | p. 307 |
Outlook and perspectives | p. 308 |
Conclusions | p. 312 |
Appendix | p. 312 |
Acknowledgments | p. 315 |
References | p. 315 |
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