Classical Theory | |
Thermoelasticity from the Continuum Viewpoint | p. 3 |
Introduction | p. 3 |
Kinematics of Continua | p. 4 |
Mechanics | p. 9 |
Thermodynamics | p. 15 |
Various Thermodynamic Potentials | p. 24 |
Thermoelastic Stress-Strain Relations | p. 27 |
Thermoelastic Relations for Small Changes from Reference State | p. 30 |
Related Thermodynamic Functions | p. 34 |
Elastic Constants in Terms of Displacement Gradients | p. 38 |
Isotropic Solids | p. 42 |
Notation of Thurston (1964) | p. 47 |
Concepts of Classical Statistical Mechanics | p. 49 |
Introduction | p. 49 |
Hamiltonian Mechanics | p. 50 |
Use of Statistics in Statistical Mechanics | p. 54 |
Phase Functions and Time Averages | p. 56 |
Phase Space Dynamics of Isolated Systems | p. 61 |
Systems in Weak Interaction | p. 72 |
Canonical Distribution | p. 76 |
Time Averages versus Ensemble Averages | p. 80 |
Corresponding Concepts in Thermodynamics and Statistical Mechanics | p. 85 |
Introduction | p. 85 |
Empirical Temperature | p. 87 |
Quasi-Static Process | p. 88 |
Phase Functions for Generalized Forces | p. 89 |
First Law of Thermodynamics | p. 90 |
Second Law of Thermodynamics | p. 93 |
Use of Mechanical Variables as Controllable Parameters | p. 96 |
Fluctuations | p. 104 |
Partition Function Relations | p. 115 |
Continuum Formulations of Nonuniform Processes | p. 116 |
Equipartition Theorem | p. 118 |
Entropy from the Information Theory Viewpoint | p. 120 |
Crystal Elasticity | p. 127 |
Introduction | p. 127 |
Bravais Lattices | p. 129 |
The Atomistic Concept of Stress in a Perfect Crystal | p. 131 |
Harmonic and Quasi-Harmonic Approximations | p. 140 |
Thermoelastic Stress-Strain Relations Based on the Harmonic Approximation | p. 143 |
Cauchy Relations | p. 150 |
Stress Ensemble | p. 156 |
Linear Chain with Nearest Neighbor Interactions | p. 160 |
Lattice Dynamics and Crystal Elasticity | p. 174 |
Rubber Elasticity, I | p. 185 |
Introduction | p. 185 |
Relative Roles of Internal Energy and Entropy | p. 186 |
Atomic Structure of Long-Chain Molecules and Networks | p. 188 |
One-Dimensional Polymer Model | p. 193 |
Three-Dimensional Polymer Models | p. 198 |
Network Theory of Rubber Elasticity | p. 205 |
Rubber Elasticity, II | p. 211 |
Introduction | p. 211 |
Curvilinear Coordinates | p. 212 |
Geometric Constraints | p. 217 |
An Example | p. 221 |
Curvilinear Coordinates for Stressed Polymer Chains | p. 223 |
Rigid and Flexible Polymer Models | p. 228 |
Use of S = k log p for Stretched Polymers | p. 234 |
Strain Ensemble for Short Freely Jointed Chains | p. 237 |
Stress Ensemble for Chain Molecules | p. 244 |
Statistical Mechanics of Phantom Networks | p. 247 |
Addendum: Atomic View of Stress in Polymer Systems | p. A1 |
Rate Theory in Solids | p. 257 |
Introduction | p. 257 |
Impurity Atom Diffusion | p. 258 |
A Simple One-Dimensional Rate Theory | p. 261 |
Exact Normalization | p. 265 |
Many Degrees of Freedom | p. 267 |
Transition-State Assumption | p. 275 |
Brownian Motion | p. 276 |
Kramers Rate Formula | p. 287 |
Quantum Theory | |
Basic Concepts of Quantum Mechanics | p. 297 |
Introduction | p. 297 |
Structure of Classical Mechanics | p. 298 |
Structure of Quantum Mechanics | p. 299 |
Consequences of the Fourier Transform Relation between [psi subscript x](x) and [psi subscript p](p) | p. 303 |
Extension to Three-Dimensional Motion and to N Particles | p. 312 |
Hydrodynamic Analogy to Quantum Mechanics | p. 315 |
Initial-Value Problems | p. 318 |
Aspects of the Measurement Process | p. 320 |
Some Examples of Stationary States | p. 322 |
Tensor Product of Two Spaces | p. 334 |
Electron Spin | p. 336 |
Identical Particles and the Pauli Principle | p. 340 |
Interatomic Interactions | p. 347 |
Introduction | p. 347 |
Hydrogen Molecule | p. 348 |
Adiabatic Approximation | p. 353 |
Hellmann-Feynman Theorem | p. 357 |
Harmonic Elastic Moduli Based on Hellmann-Feynman Theorem | p. 360 |
Categories of Interatomic Force Laws | p. 365 |
Quantum Statistical Effects | p. 372 |
Introduction | p. 372 |
Quantum Statistical Mechanics | p. 372 |
Quantum Statistical Effects in Crystals | p. 386 |
Quantum Statistics for Polymer Models | p. 403 |
Gaussian Wave Packet Dynamics | p. 406 |
Canonical Ensemble in Terms of Coherent States | p. 412 |
Quantum Effects on Rate Processes | p. 416 |
References | p. 421 |
Index | p. 431 |
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