Preface | p. xi |
Preface | p. xiii |
Production of Fullerenes | |
Introduction | p. 1 |
Interstellar Absorption and Emission Features | p. 1 |
Preparation of Fullerenes | p. 4 |
Early Work on Graphitic Particles | p. 4 |
New Forms of Carbon | p. 7 |
Further Developments | p. 12 |
Fullerene Formation | p. 13 |
Initial Molecular Growth | p. 14 |
Molecular Shapes | p. 16 |
Building Blocks | p. 17 |
Annealing | p. 18 |
Molecular Growth to Fullerenes | p. 19 |
Outlook | p. 20 |
Intercalation Compounds of Fullerenes I: Synthesis, Characterization, and Solid State Properties | |
Introduction | p. 23 |
C[subscript 60] As a Host Lattice for Intercalation | p. 24 |
Synthesis | p. 34 |
High-Temperature Synthesis | p. 36 |
Low-Temperature Synthesis | p. 39 |
Characterization | p. 42 |
Titration | p. 42 |
Differential Scanning Calorimetry | p. 42 |
Raman Scattering | p. 43 |
Magnetic Resonance Techniques | p. 44 |
X-Ray Diffraction | p. 46 |
Neutron Scattering | p. 47 |
C[subscript 60] Intercalated with Neutral Species | p. 48 |
Intercalation of Gases into Solid C[subscript 60] | p. 49 |
I[subscript 2] Intercalated C[subscript 60] | p. 54 |
P[subscript 4] Intercalated C[subscript 60] | p. 58 |
Ferrocene Intercalated C[subscript 60] | p. 60 |
AsF[subscript 5] Intercalated C[subscript 60] | p. 61 |
Intercalation Compounds of Fullerenes II: Structure and Superconductivity of Alkali Metal Fullerides | |
Introduction | p. 67 |
Structure of K, Rb, and Cs Intercalated C[subscript 60] | p. 69 |
AC[subscript 60] | p. 69 |
A[subscript 3]C[subscript 60] | p. 71 |
A[subscript 4]C[subscript 60] | p. 75 |
A[subscript 6]C[subscript 60] | p. 79 |
Sodium Intercalated C[subscript 60] | p. 82 |
Low Na Concentration 0 [ x [ 3 | p. 84 |
Intermediate Na Concentration 3 [ x [ 6 | p. 87 |
High Na Concentration x ] 6 | p. 88 |
Na[subscript 2]MC[subscript 60] Phases with M = A, Cs[subscript 1-x]Rb[subscript x], Hg[subscript x], etc. | p. 93 |
Lithium Intercalated C[subscript 60] | p. 96 |
Ammoniated A[subscript x]C[subscript 60] | p. 101 |
Alkaline-Earth Substituted A[subscript x]C[subscript 60] | p. 105 |
A[subscript 3-x]Ba[subscript x]C[subscript 60] (0 [ x [ 2) | p. 106 |
A[subscript 3-y]A'[subscript y]Ba[subscript 3]C[subscript 60] (A, A' = K, Rb, Cs) | p. 112 |
Superconductivity | p. 116 |
Introduction | p. 116 |
The Relation between T[subscript c] and Inter-molecular Separation | p. 117 |
The Relation between T[subscript c] and Band Filling (C[subscript 60] Valence) | p. 123 |
Non-cubic Superconductors: Cs[subscript 3]C[subscript 60] and NH[subscript 3]K[subscript 3]C[subscript 60] | p. 126 |
Experimental Studies of the Electronic Structure of Fullerenes | |
Introduction | p. 135 |
Structural and Theoretical Background | p. 136 |
The Archetype Fullerene C[subscript 60] | p. 136 |
Higher Fullerenes | p. 138 |
Doping of Fullerenes | p. 139 |
Experimental Details and Spectroscopic Techniques | p. 141 |
Sample Preparation | p. 141 |
Electron Energy-Loss Spectroscopy | p. 142 |
Photoemission Spectroscopy | p. 142 |
Pristine Fullerenes: From C[subscript 60] to C[subscript 84] | p. 143 |
Intercalated Fullerenes | p. 149 |
Alkali Metal Intercalation | p. 149 |
Alkaline-Earth Intercalation | p. 158 |
Heterofullerenes | p. 160 |
Endohedrally Doped Fullerenes | p. 164 |
Concluding Remarks | p. 167 |
Polymer and Dimer Phases in Doped Fullerenes | |
Introduction | p. 175 |
Bridged Fulleride C[superscript - subscript 60] Ions in AC[subscript 60] Salts | p. 176 |
Bridged Fulleride C[superscript 3- subscript 60] Ions in Na[subscript 2]AC[subscript 60] Salts | p. 181 |
Bridged Fulleride C[superscript 4- subscript 60] Ions in the Na[subscript 4]AC[subscript 60] Salt | p. 190 |
Bridged Heterofullerenes and Their Derivatives | p. 192 |
Conclusions | p. 199 |
Vibrational Properties of Fullerenes and Fullerides | |
Introduction | p. 203 |
Symmetry and Vibration of the C[subscript 60] Molecule | p. 204 |
Pristine C[subscript 60] | p. 206 |
Symmetry and Vibrations in C[subscript 60] Fullerite | p. 206 |
Results from Low Temperature Raman Scattering and IR Spectroscopy | p. 208 |
Calculation of Vibrational Frequencies | p. 211 |
Isotope Effects and Very High Resolution Spectroscopy | p. 211 |
Scattering Intensities and Resonance Profile for C[subscript 60] | p. 214 |
Inelastic Neutron Scattering in C[subscript 60] and Lattice Modes | p. 216 |
Vibrational Spectroscopy of Fullerides | p. 217 |
Raman Spectra of Charged C[subscript 60] | p. 219 |
Vibrational IR Spectra of Charged C[subscript 60] | p. 221 |
Electron-Phonon Coupling | p. 221 |
Theoretical Description of the Vibrating C[superscript -N subscript 60] | p. 222 |
Higher Fullerenes, Endohedrals, and Heterofullerenes | p. 224 |
Higher Fullerenes | p. 225 |
Endohedral Fullerenes | p. 226 |
Heterofullerenes | p. 228 |
Polymers and Dimers | p. 229 |
Symmetry and Polymerization | p. 230 |
Vibrational Spectra of Neutral Polymers | p. 231 |
Charged Fullerene Polymers | p. 238 |
Conclusion | p. 244 |
Intercalation Compounds of Fullerenes III: Other Fullerides and Intercalated Nanotubes | |
Alkaline-Earth Doped C[subscript 60] | p. 249 |
Ca-Doped C[subscript 60] | p. 250 |
Ba-Doped C[subscript 60] | p. 252 |
Sr-Doped C[subscript 60] | p. 256 |
Rare-Earth and Lanthanide Metal Intercalated C[subscript 60] Compounds | p. 257 |
Yb-Doped C[subscript 60] | p. 257 |
Sm-Doped C[subscript 60] | p. 261 |
Eu-Doped C[subscript 60] | p. 264 |
Solid C[subscript 70] and its Intercalation Compounds | p. 265 |
Solid C[subscript 70] Host Lattice | p. 265 |
Intercalation Compounds of Solid C[subscript 70] | p. 270 |
Carbon Nanotube Intercalation Compounds | p. 274 |
Introduction | p. 274 |
Single-Walled Carbon Nanotube Bundles | p. 275 |
Intercalated Multiwalled Nanotubes | p. 280 |
Intercalated Single-Walled Carbon Nanotube Bundles | p. 282 |
Summary and Prospects | p. 285 |
Structural and Electronic Properties of C[subscript 60] and C[subscript 60] Derivatives in the Solid Phases: Calculations Based on Density-Functional Theory | |
Introduction | p. 291 |
Solid C[subscript 60] | p. 292 |
Alkali-Metal and Alkali-Earth-Metal Fullerides | p. 295 |
(K,Rb)[subscript x]C[subscript 60]; x = 3, 4, 6 | p. 296 |
Na[subscript x]C[subscript 60]; x = 6, 10 | p. 306 |
Alkaline-Earth-Doped Fullerides | p. 312 |
(K,Rb)[subscript 1]C[subscript 60] Polymeric Phases | p. 318 |
Alkali-Metal Intercalated Heterofullerenes: K[subscript 6]C[subscript 59]N | p. 322 |
Computational Details | p. 324 |
C[subscript 60] | p. 324 |
(K,Rb)[subscript x]C[subscript 60]; x = 3, 4, 6 | p. 325 |
Na[subscript x]C[subscript 60] | p. 325 |
(Ca, Sr, Ba)[subscript x]C[subscript 60] | p. 325 |
(K, Rb)[subscript 1]C[subscript 60] | p. 326 |
K[subscript 6]C[subscript 59]N | p. 326 |
Carbon Nanotubes | |
Carbon Nanotubes | p. 331 |
Synthesis | p. 334 |
Structure of Carbon Nanotubes | p. 338 |
Electronic Structure | p. 341 |
Transport Properties | p. 348 |
Phonon Modes | p. 354 |
Raman Spectra | p. 363 |
Mechanical Properties | p. 372 |
Applications | p. 374 |
Electronic Structure of Carbon and Boron-Carbon-Nitrogen Nanotubes | |
Introduction | p. 381 |
Structure and Properties of Carbon Nanotubes | p. 382 |
Structure and Properties of Boron-Carbon-Nitrogen Nanotubes | p. 389 |
Nanotube Junctions and Nanoscale Electronic Devices | p. 394 |
Encapturation, Nanoribbons, and Ropes | p. 400 |
Summary | p. 405 |
Pressure Studies on Fullerenes | |
Introduction | p. 409 |
Physical Properties of Fullerenes under Pressure | p. 410 |
In-Situ Structural Measurements under Pressure | p. 410 |
Optical Measurements under Pressure | p. 412 |
Thermal and Transport Measurements under Pressure | p. 413 |
Phases Obtained from Fullerenes under Pressure | p. 417 |
Phases Conserving the Cage Structure: Polymerised Structures | p. 417 |
Phases Obtained after Collapse of the Fullerene Cage | p. 427 |
The Phase Diagram of C[subscript 60] | p. 435 |
Conclusions | p. 438 |
Index of Materials | p. 443 |
Table of Contents provided by Syndetics. All Rights Reserved. |