Theoretical Aspects of Transition Metal Catalysis

By: Gernot Frenking (Editor)

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Hardcover | 23 June 2005

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280 Pages

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23.39 x 15.6 x 1.75

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Transition metal catalysis belongs to the most important chemical research areas because a ubiquitous number of chemical reactions are catalyzed by transition metal compounds. Many efforts are being made by industry and academia to find new and more efficient catalysts for chemical processes. Transition metals play a prominent role in catalytic research because they have been proven to show an enormous diversity in lowering the activation barrier for chemical reactions. For many years, the search for new catalysts was carried out by trial and error, which was costly and time consuming. The understanding of the mechanism of the catalytic process is often not very advanced because it is difficult to study the elementary steps of the catalysis with experimental techniques. The development of modern quantum chemical methods for calculating possible intermediates and transition states was a breakthrough in gaining an understanding of the reaction pathways of transition metal catalyzed reactions. This volume, organized into eight chapters written by leading scientists in the field, illustrates the progress made during the last decade. The reader will obtain a deep insight into the present state of quantum chemical research in transition metal catalysis.

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You Can Find This Book In

Non-Fiction Engineering & Technology Industrial Chemistry & Manufacturing Technologies Metals Technology & Metallurgy Science Chemistry Inorganic Chemistry Physical Chemistry Organic Chemistry Organometallic Chemistry

Transition metal catalyzed [sigma]-bond activation and formation reactions	p. 1
Theoretical studies of C-H [sigma]-bond activation and related reactions by transition-metal complexes	p. 31
Enantioselectivity in the dihydroxylation of alkenes by osmium complexes	p. 79
Organometallacycles as intermediates in oxygen-transfer reactions. Reality or fiction?	p. 109
Late transition metals as homo- and co-polymerization catalysts	p. 145
Co-oligomerization of 1,3-butadiene and ethylene promoted by zerovalent 'bare' nickel complexes	p. 187
The cluster approach for the adsorption of small molecules on oxide surfaces	p. 219
Table of Contents provided by Blackwell. All Rights Reserved.

Theoretical Aspects of Transition Metal Catalysis

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